Oh for the grain.

It is a fact of life for film users, if it was not for the those tiny light sensitive particles we would not have some of the world greatest pictures. All the same overly grainy negatives are a pain if you have not planned for it to happen it's a big let down. You must not forget that it is not all about the journey it is about the results as well and what looks like rubbish to you now. Maybe an inspired choice to others.

The fact you have a negative to look at is a result and something that will print and or scan. At one time grainy pictures were all the rage. Producing some wonderfully expressive images. Admittedly they are not everyone's cup of tea. In other words keep an open mind.

The object of developer is to bring out the latent image held in the emulsion. This is achieved by a chemical reaction, acting on the silver, producing dark areas where it is light and bright areas where there is shadow. The negative is reversed later with the print. There are three important things to keep at the front of your mind are: the development time, the temperature and dilution. It is these three factors that ensure the ultimate image quality when it comes to printing. Too short a development time will produce too thin a negative, like wise too long a process time will make the negative too dense, leading to very short and very long print times respectively.

Agitation is important as well and one of the most over looked parts of the film development, it can in some cases make the difference in how well your negatives turn out. As the developer interacts with the emulsion of the film, it vigorously attacks the silver it comes into contact with and becomes exhausted. By inverting the tank you refresh this action, producing evenly developed negatives. It is important to get this right. To little agitation will allow by-products of the process to build up, leaving pale-toned streamers as they slide to the bottom of the film. Likewise excessive inversions will produce currents in the developer, creating uneven development. Most process times allow for agitation.

Developers:

The first thing to look at is the developer. This has the most influence over how your negatives will look. Before you settle on one in particular make sure you understand its attributes. On a practical note you also need to know how often you will process a film. If you are going to process a film every week or so then it may be better to use one in powder form like ID11 or D76. Or a one shot liquid for occasional use, like Ilfotec HC or Kodak HC110. I have suggested these developers because they are main stream fine grain developers. RO9 is not recognized as a fine grain.

For example:

Ilford ID11: A full speed developer with fine grain. Supplied as a two pack powder. Down side is that you have to make up 5 liters of stock solution. This then leads to question over it's keeping qualities. ( I have taken a year to use a 5ltr batch without any loss of quality) It can be used as one shot or multi use with allowance for depletion. ( I have only ever used as a one shot.)

Ilfords Ilfotec HC: A highly concentrated, fine grain liquid developer. It is suggested that this is the liquid equivalent to ID11.

Kodak D76: Fine grain developer recognized as Kodak's ID11. It has been reformulated as a one pack powder. The down side is that it needs very hot water to mix it easily.

Kodak HC 110: A fine grain sharp working developer. In a highly concentrated liquid syrup form. This is Kodak's answer to ID11/D76 as a liquid.

One more developer to what could be a very long list and that is:

RO9 Special/ Studional. These are the finer bred brothers of RO9 and Rodinal. They are very concentrated liquids with the good keeping qualities you would expect from this family. 

The unexpected.

It is the developer you choose that has the most influence over what your negatives and grain looks like. Inter mixed with the way you apply the agitation method you adopt and making sure that the temperature is right. Master this and the rest will fall into place. Yes you will make mistakes we all do even with years and years of experience it is all part of the rich tapestry of processing. It is and can be a pain when the results effect that special set of negatives. I know, it's that spanner that has landed with a big thud at times. The trick is understanding what went wrong, then put it right and move on. Now a days there is no such thing as a bad set of negatives - just conceptually challenging. You just have to look at all the apps you can get now that put back all things analogue photographers try to avoid. So what maybe unacceptable at first will change over time.

Really what I'm saying is to keep an open mind, the analogue process can, if you embrace it, give an unexpected creative lift to your images. Which today is more acceptable than it used to be. 

Tetenal Eukobrom AC first look

I like trying new things out in the darkroom, so when an offer to use Tetenal's new monochrome paper developer Eukobrom AC came up I jumped at it. I would like to thank Matt of AG Photographic and Tetenal for the chance to be one of the first to give it a test drive. A few weeks later a package arrived at the door, since then I have been chafing at the bit to try it out.

This is a new developer made for twenty first century. It is also the first commercially to use isoascorbate, vitamin C (you're not seeing things) as the main developing agent, it is a direct replacement for Hydroquinone the most widely used ingredient in photographic developers, noted for it's fast action and high contrast. It is marketed as the alternative to Ilfords multigrade all purpose paper developer producing the same sort of neutral tones. The developer works with both Fiber Baryta and resin coated light sensitive papers, whether multigrade or graded.

Top row: Ilford multigrade RC paper. left side in
multigrade developer. Right side Tetenal.
Bottom row: Fomaspeed variant RC paper. 

The data at the moment is quite sparse.

Technical Data:

Fibre Baryta Paper (FB)	Dilution	20C	25C	30C
	1+4	90s	70s	50s
	1+9	100s	80s	60s
Resin coated paper	1+4	50s	30s	15s
	1+9	70s	50s	30s

All information is provided for guidance only. Deviations may arise,

depending upon the paper used. Shortening or extending the development

time by up to 10% is possible.

Diluted 1+9  Eukobrom

In to the Darkroom.

The first thing you notice with this developer is it's lack of odour. The next is the colour of the liquid, a rich yellow. I decided to dilute at 1+9. Once done I poured the contents of the measuring jug into a tray. I would have used my up right paper processor but that already had fresh Ilford multigrade in it. Using the tray for the new developer would allow me to note how long it took for the image to start appearing.

The comparison.

I have several makes of light sensitive paper in stock. I chose three, the most obvious Ilfords multigrade, Fomaspeed Variant 311 and Kentmere VC select gloss, all resin coated papers. I went to these first as they are reasonable quick to process and give an insight into how the Eukobrom will perform. Before moving on to FB papers. (results to follow in another post)

The set up.

I chose a negative from a recently developed set of Agfa APX100. I set the height of the enlarger so it would produce an enlargement of 9 x 12 then set the easel to 8x10. I did this because the Kentmere paper I wanted to include I only had in 9x12, this would keep everything consistent.

Ilford multigrade RC  paper
 developed in Tetenal developer

 

 

The test strip was processed in the multigrade developer and it was indicating that the image would need to be dodged, if I wanted a picture I was happy with. I set the enlarger as follows lens F8, grade 3, exposure: The whole image was exposed for twelve seconds, the sky from the bridge upwards plus eighteen seconds and finally the sky from half way up to the top of the image plus eighteen seconds. I would produce two pictures on each paper all at the same setting. The developers temperature was set at 20C.

Ilford multigrade RC
 Paper developed in Multigrade

 

Results:

Both developers are advertised as neutral tone. To me this means they are subtlety on the cool side.

The differentiation started with:

• The Ilford paper when compared with the other papers in the test, has a slight warmth to it's tone when developed in fresh multigrade. The Eukobrom is slightly cooler in look with a more intense black and crisper whites giving it a bit more contrast.
• The Fomaspeed paper has a cooler look to it when developed in multigrade compared to the Ilford paper. The Eukobrom proved to be cooler looking again with more intense blacks and clearer whites again adding to the contrast.
• The Kentmere paper is known to have a higher contrast level to the previous papers mentioned maybe as much as a grade. When developed in multigrade the image had a muddy look to it indicating over exposure with a slightly warm feel to it. The Eukobrom processed image had a cleaner crisper look. Again the midtones had better separation making it look more like a moon light picture instead of over exposed.

Fomaspeed variant RC
 developed in Tetenal

 

Once you understand that Eukobrom adds contrast to the image possibly more so than the Hydroquinone it replaces. It is easy to allow for by reducing the grade you would normally use. The blacks are wonderfully rich giving the pictures some real punch. The mid tones have more separation than Ilford multigrade but the surprise is the brightness of the whites.

Fomaspeed  variant RC
developed in Multigrade

Personally the main questions yet to be resolved are its keeping qualities and whether or not the image will be warm when the developer starts to deplete.

Kentmere paper.
Top Row: exposed at grade three.
Right side Tetenal developer. Left multigrade.
Bottom row: exposed at grade two.

 

This is a nice developer to work with for prolonged periods as you do not get that developer smell lingering up your nose afterwards. Oh! It does look like OJ when diluted so keep it out of the reach of kids. It is a real gem and I will be ordering a bottle, it may even replace my favorite multigrade! Don't take my word for it try it for yourself you will not be disappointed. 

RO9 special/studional six months from dulition.

Fomapan 200 test negatives.

I'm now six months down the line with this litre of RO9s/Studional and nine completed developments to date. With it now being three months on from it's suggested 'best before' time I started this processing session with the last seven frames from my out of date Fomapan 200, to check that the developer was still viable.

 The Fomapan was in the developer for eight minutes this included the 20% compensation for developers age. For me anyway this developer was now in completely unknown territory and the 20% adjustment was under review again. Although the last time I used the developer the urge to increase was very strong, I considered it again and dismissed the idea very quickly this time. Remembering what I had said last time.

Agfa APX 100 negatives

As soon as the film had been fixed I pulled it out of the developing tank to check. On first look it looked like it had not worked but on closer inspection there was a very good looking negative peering back at me. Great! Now I can get on with the others.

including the 20% and a roll of Fomapan 400 which stopped me in my tracks for a while as I had no suggested development times for it. Ah! What to do? I was processing this for someone else. Don't panic Mr Mannering. I checked through the Massive dev charts 400 ISO film times for Studional with dilutions of 1+15. It was saying that between four and eight minutes. Which is quite a leeway to pair down. I then looked at the Agfa and Rollei times for 400 ISO film to try and shrink the time difference. This helped a lot, it was suggesting five and a half minutes as an average. So me being me rounded it up to six and added 20% which worked out at a bit over seven minutes.

 I intended to develop for seven minutes and ended up doing eight I was interrupted loosing track of the time. It is possible that the mix up has made for a better developed set of negatives which may have worked in my favour this time. Which leaves a dilemma for the next roll - what time should I use?

Fomapan 400 negatives

All in all this out of date developer has proved its self to be a good performer, out of the three newly processed film the Fomapan 200 is disappointing in that the negatives are a bit thin. Some of this is to do with bad exposure and not the development. On closer inspection of this last length of film it looks as though the surface has been contaminated with sweaty finger marks, some scratches and a lot of dust marks on the negatives. Not surprising really seeing that the film has been cut into sections on three other occasions.

It turns out that the Agfa APX 100 has been over developed. I have also noted that the negatives are a bit more grainy than they should be. This could be the down side of using the RO9s outside the three month best before date.

So what now? The developer is good for another three film but I think it will be discarded for a new batch. The reason for using this developer in the first place is because of it's finer grain. If I want it coarse looking I'll use RO9.

Looks like coffee not multigrade?

Ilford multigrade paper developer

It has been sometime since I have entered the orange light district. Upon entering recently the darkroom looked a mess, something I don't remember leaving.! It could do with a good clear out and clean up but that will have to wait. I'm in desperate need of print therapy. I do a quick clean of the enlarging easel and lens. Then check the chemicals in the paper processor.

 The developer has gone a very deep brown, the stop and the fix look OK they were all fresh the last time. Even so I change the fix. Now what to do about the dev? In the end I emptied out half so I could refill it with fresh. Your thinking 'it's knackered why bother?' but I prefer the tone you get when fresh and old are mixed together. The slight depletion gives a warmth to images I like.

Contact prints.

I opened a partly used bottle of Ilford multigrade and poured out some of the contents to be met by a liquid the colour of black coffee! That's a new one on me never had that before! Which makes me think - ( expletive ) Mmmm! I'll use it anyway see what happens. I do not have a choice as I do not have a fresh bottle on the shelf.

First test print

It was my intention to get on with some enlargements, but I decide to contact print three sets of freshly developed 35mm negatives as this will test the strength of the developer. It turns out that the dev is more depleted than I had expected ( you were right). The contacts are taking nearly two minutes to reach full development and that is a very long time for resin coated paper, which is usually fully done in a minute.

Before I start work on the enlargements I drain another litre of developer and add some more 'black coffee' (developer) to the mix. Then load the first negative into the enlarger. I find I can be a little apprehensive getting ready to do my first print after a long absence. I'm not sure why, as it always works well.  

Second test print

With the first test strip exposed, into the dev it goes. Ah! I was a little quick off the mark the developer has not reached 20C yet as it takes a little over a minute to fully develop. As it turn out the test strip shows that I was being optimistic with the F8 aperture I had set. The test strip is not showing any exposure in the first four, five second segments. Indicating it will take more than fifty seconds to reach a base exposure time. That's far to long so, I adjust it to F5.6 effectively doubling the light. The next test strip I start at fifteen second and go on from there at five second intervals. Sometimes I can over develop the negatives and this is the first indication of it. Which I don't mind. The trick is not to over do it as it leads to loss of detail. That's better! the test strip was fully developed in less than a minute.

How the areas were dodged showing
how much extra light was added to each
section

With the second test strip in the holding try I take my time looking at the segments. My vision for the image has already formed and with a plan. All I need now is get off the fence and decide what time the first print should be exposed at. I plump for twenty two seconds at F5.6 at grade three on Kentmere RC gloss 9x12. I have already noted that the Ro9s negatives are a little softer than the normal Ro9 and not as grainy.

I need to point out here that I always work from wet test strips and automatically add a dry down factor without thinking. Ansel Adams used to tell a story of how he came to recommend that you should always work from dry test strips and prints. He had produced a particular photograph that was a delight to the eye so much so that he went ahead and printed a large number of them. Only to throw the whole lot out the following day as they did not look as good as when they were wet. I don't very often do long print runs and if I do it is not until I have studied the print dry in day light.

Final print.

As I look at the photograph in the holding tray with the rooms light on I can see it is over exposed, dull and muddy looking. It lacks the luminosity I have come to expert from analogy prints.

I already new that the picture would need dodging to recreate my vision. I inspected the test strip again and cut the overall exposure time to fifteen seconds. I then dodged the foreshore and wooden posts while I added a further seven seconds to the water above them and the sky.

 

Again I studied the second print in the holding try. Although it had improved, It still fell short of my vision. It is a good idea to have a notebook to hand in the darkroom so you can keep track of the adjustments. I have now cut the overall exposure to eleven seconds. I will add a further seventeen seconds in three sections. First of all I will add four sec's from the edge of the water to the rest of the picture. Next, seven sec's from where the wooden posts finish and finally seven more seconds to the upper part of the sky.

These last adjustment have improved the image no end. Bringing it very close to what I had in mind and giving it the luminosity it lacked. There maybe some fine tuning needed when I print it on FB paper but I will only do that once the photograph is fully dry.

With the three prints side by side
You can see how the image has changed.

The coffee coloured developer has worked well even with the heavy oxidation of liquid. A change in colour does not always mean it has lost it's potency. Now that the photograph is dry the image has a very gentle warmth to it. I have found that the tone a photograph takes is more pronounced once it is fully dry.

 

Redeveloping the negative.

You will at some point in your developing career, come across a negative(s) that has so much contrast that no matter what you do, you cannot get a decent print. There is a method you can use to retrieve the situation by redeveloping the negative(s).

To start with you will need to make up a solution of halogenizing bleach as follows:

• 10 grams of Potassium permanganate.
• 10 grams of Potassium Bromide.
• 1 litre of cool water.
• Stir this until all is dissolved in the water.

This can be carried out in a normally lit area so you can see the change in the negative. It takes about 5-7 minutes for the black silver on the film to be converted to a yellowish precipitate. You can remove the film from the bleach when the strongest high lights have gone a pale grey and wash well in running water. Now place in a soft compensating developer. When the highlights return to a greyish yellow remove the film and place in an acid stop bath for 30 seconds. Then fix, wash and dry as you would normally. This should produce a softer easier negative to print.

It is probably better to use a farmers reducer which subtracts the density from a

processed negative.They come ready mixed, you only add the right amount of water. This process can be repeated as many times as needed to get the right density; it's not a one shot approach. Allowing you to do a test print at each stage. There are three to types:

• Kodak R-4a is best used for over exposed negatives and is easy to control. Acts on shadows first, then mid-range and then highlights. Mainly used for clearing fog from film and reducing prints.
• Kodak R-4b is best for over developed negatives; it removes equal amounts of deposited silver from the highlight and shadow areas.
• Kodak R-15 This is a super reducer, striping the highlights and not the shadows. For seriously over developed negatives and is the most difficult to control.

This is just a basic outline on the subject and will require further reading.

RO9 and the lens less camera.

All the photo's side by side

Over the last few months it looks like I have gone RO9s mad. I have! it is the new toy in my developing arsenal. I'm enjoying the quality of the negatives and not having to make up developer every time I want to process a film. It is still new enough for me to think I have forgotten to do something as I pour the liquid in the developing tank. With all this effort being spent on this developer it has made me think about its brother RO9 and it's attributes in connection with pinhole photography.

Image from PMK Pyro developed negative printed
on Ilford multi grade RC gloss.

Let me explain: RO9 is described as having a number of qualities, the main one here being, high acutance producing a very sharp looking image - a bit like sharpening a digital file in Photoshop. The idea that this developer may do this to the processed negatives has been a splinter in my mind for sometime, that I have been compelled to dust off my Zero pinhole camera to find out if it does make a difference.

Image from RO9 developed negative.
Printed on Kentmere RC gloss

I always feel very relaxed after I have spent time making images with this camera, I should use it more often. Anyway I loaded it with Fomapan 100 set to a 6x6 negative size.

 With the twelve images made it was into the darkroom to process the film. It was developed in the RO9 for thirteen minutes. The density of the negatives was as expected. With the new crisp looking negatives hanging up to dry what should I compare them with? After searching back in my archive of negatives it looks like the only other developer I have used when making images with the Zero is PMK Pyro. This developer is not known for it's sharpness but at least I did not follow the method through by using an afterbath. Which can add a further softening of the image by adding tone.

Zero pinhole set to 6x6 120 negative size

My comparison was never going to be very scientific. It was always going to be a case of would I be able to see a difference with the naked eye. You may feel that the comparison is unfair and to a certain extent you are right. To counter this I will compare the RO9 negatives with those produced with a lensed camera. If the RO9 is a sharpening developer it should be noticeable.

Image made using a camera lens.
35 mm Agfa APX 100 developed ID11

When looking down the focus finder at the different developed negatives the difference in grain structure jumps out at you. The PMK Pyro neg's are so smooth it is difficult to bring the the grain into sharp focus. Where as the RO9 grain looks like boulders. So does this defined structure indicate that the negatives will be sharper?

I enlarged the negatives to fill the 9 x 12 Kentmere RC gloss paper, instead of the smaller 6X6 square format of the negative. I wanted to see if the grain would be more exaggerated by doing this. To my surprise they lack the graininess I was expecting. In fact they are very smooth and defined.

RO9 developed negative printed
on Kentmere RC gloss

Conclusion:

With all the photographs laid out side by side is there a visual difference in sharpness? The straight answer is Yes but not enough to say if you want sharper lens-less images use Ro9. When you compare the PMK negatives with the RO9 ones there is slightly better definition to the edges of the subject giving you the sense that the pictures are sharper. It does not take away that distinct soft focus you get with pinhole cameras. If you then put a lensed print beside the RO9 developed picture you can see that it is very soft in the pinhole tradition. It shows that when using RO9 there is a sharpened quality to the photographs.

PMK Pyro developed image printed on Fomaspeed
Variant 131

  

Instant Photographs.

When I heard about the demise of Polaroid. I was saddened, to think that at one time I had a Polaroid camera in my car all the the time, along with a dozen packs of film (the peal apart type). In those days if I only made 50 images in a week I classed it as a slow period. With Polaroids announcement I had the sudden urge to make a few pictures before it disappeared. Sadly I could not find my camera, then remembered that I had given it away.  

About ten or so years ago we acquired an Instax 200 instant camera that has sat in my camera cupboard. It would still be sitting there gathering dust if it had not been for a marketing email from Lomography stating the camera and film were available again.

Some weeks later I was in town, so I dodged into my local Snappy snaps to see if they had the film in stock. They did, so I purchased a box - not a cheap venture now a days!

The camera has been boxed all this time and is brand new to look at apart from a broken battery cover. To my surprise there was still a film in it. I put batteries in it, took a picture and out popped an oblong card. Then waited to see if an image would appear, Alas after a good five minutes just a slight change in colour. It was worth a try.

It was some months before I had the opportunity to use the new film in the camera. Then fortune smiled and what a cracking day it was. At the time, it was a leap in the dark as I have never used this camera before. I lost a couple of frames to bad composition and to under development which can be adjusted in the camera settings. It did not take long to catch on. As you can see from the pictures.

The panoramic view the cameras produces has a distinct look to them.

 

RO9 special/ Studional three months on.

Out of date Fomapan 200

Another month on and I'm back to using the turquoise Studional and a further cutting from the Fomapan 200, only this time there are couple of dozen images to muck up. The chances of something going wrong diminishes as you get used to the way the developer works, the only spanners are out of date film and senior moments, if it all go's wrong I may learn my lesson.

Out of date Fomapan 200

So far the developer has been used seven times without it missing a step. When comparing the negatives with the naked eye or in this case a magnifier the density between the batches looks to be identical. As far as the compensation factor is concerned this is uncharted territory for me. The question is, does 20% allowance still apply two months on? Thinking on it carefully the answer is yes. My reasoning is that to increase it without knowing whether the suggested compensation worked or not does not make sense. I should test the information and not do my own thing.

 

The information on this developer states that once it is diluted one litre should be good for three months or 12 film processes which ever you arrive at first if stored properly. I will admit that the bottle this is stored in is to big leaving an air gap that will allow the developer to deteriorate more quickly according to the data sheet. I have not done this on purpose I didn't have a container the right size and yet it still works well. Obviously it is better to do what manufacturer recommends to get the best results but in the real world we all make compromises. So is it such a surprise that I'm getting good results? The real test will be at four, five or six months after dilution.

Out of date Fomapan 200

 I processed the negatives as previously mentioned and the results are just as good so much so that I also developed a roll of Agfa APX 100. It just so happens that the dilution for this film is 1+15 (the same as HP5+) or 1+31 for 4 and 8 minutes respectively at 100 ISO. With the 20% adjustment added it took all of five minutes in the developer to receive another set of good looking negatives.

 

 

 

The more I use this developer the more impressed I am with it.

 The table below shows ten popular film that use the 1 +15 dilution. The ones marked with * are the ones I have had good results with at the suggested times with the compensation added.

The double ** is my suggested time for this film at this dilution.

Dilution of 1+15
Film	ASA/ISO	TIME
Adox CHM125	100	3.5
Agfa APX 100 *	100	4
Fomapan	100	10
Fomapan **	200	6
FP4+ *	125	4
HP5+ *	400	4
Neopan	400	6
PAN F+	50	3
Rollei Retro S	400	8.5
Tri-X	400	05/03/05

All the images that appear in this post were Developed in RO9 special
Studional.

This image is from the Agfa APX 100 film mentioned.